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The activation barrier reported for the channel cluster is 12.63 kcal/mol.
We use a machine learning algorithm to cluster the estimated channels into several groups and to select the channel cluster heads (CCHs) for feedback.
Density functional theory (DFT) calculations are employed to study N2O decomposition on relaxed [(SiH3 4AlO4M] (where M = Fe, Co) cluster models representing Fe- and Co-ZSM-5 surfaces and Fe-ZSM-5 channel cluster.
The activation barrier for the decomposition of the first N2O molecule inside a Fe-ZSM-5 channel cluster increases in comparison with that of the cluster model indicating a channel effect on the activation barrier.
The number of multipaths within each channel cluster is L p = 10.
where C is the number of channel cluster, G i is the channel gain of the i th cluster, τ i is the time constant of the i th cluster, and t d,i is the time delay of the i th cluster.
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