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The factor of main importance appeared to be the local changes of the chain length induced by the ring conformational rearrangements.
The properties of the macromolecular system were determined by means of Monte Carlo simulations with a sampling algorithm based on the local conformational changes of the chain.
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From the time dependent change of the chain orientation angle the creep strain of the fibre is derived.
This manifests itself in change of the chain shape to an 'unfolded spiral' and, therefore, stimulates increase in the conductivity [15].
The Young's modulus in the direction perpendicular to the chain axis was also found to decrease remarkably in parallel to the change of the chain packing mode.
From the change of the chain length distribution with the laser irradiation time, it is concluded that the long polyynes are produced directly from diamond particles at the initial stage of ablation.
In this regard, Quyang et al. [32] reported that the conformational changes of the PEDOT chains from the benzoid to quinoid configuration increased inter-chain interactions, thereby enhancing the conductivity of the PEDOT polymer.
Raman spectroscopy indicates that this increased interchain interaction results from conformational changes of the PEDOT chains, which change from a coil to linear or expanded-coil structure.
pH-induced infrared absorption changes of the side-chain carboxylates evidence a remarkably low pK < 3 in both strains and a structural stabilization when Pd II) is bound.
And according to the structural details, we supposed that the variations of MEPLH24, MEPLE136, MEPLV209, MEPLG210 and MEPLR213 may play curial role in the tension changes of the loop chains around the pocket of catalytic center.
To evaluate the effects of peptide binding on MHC class II structure, we used the in silico MD method to calculate spatial changes of the side-chain of the native AcN1-11 peptine in MHC pocket 6 (Fig. 1a and 1c).
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