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Changes in sizes and densities of the pre-β″ and β″ phases during ageing can explain the evolution of hardness, in particular a plateau in the curve of the hardness versus ageing time.
In such alloys, the positron trapping on free-volume entities built of pyramidal AsSe3/2 units has an obvious preference, tending the overall annihilation-like void fragmentation without notable changes in sizes of positron traps (τ 2 = ~0.36 ns) and enhanced second-component intensities I 2, in full respect to the experimental data in Table 1.
In such glassy crystalline alloys, the positron trapping on free-volume entities related to pyramidal AsSe3/2 units (as in parent As2Se3 glass) was in obvious preference, tending overall annihilation-like void fragmentation without notable changes in sizes of positron traps.
The results summarized in Table 2 indicate significant changes in sizes of the aggregates over time.
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