Exact(3)
The product selectivity could be rationalized by the changes in mechanism from dehydration v.s. dehydrogenation as the rate determining step.
Most current methods of mechanism elucidation are also unable to account for or convey changes in mechanism (ie primary and secondary targets) with changes in structure.
Nonadditive effects were generally attributed to direct or indirect interactions of the two residues mediated through the protein or changes in mechanism.
Similar(57)
All these processes are mediated by allostatic changes in mechanisms of activity-dependent synaptic plasticity, such as long-term potentiation (LTP) and long-term depression (LTD).
Genomic data can identify the nature of these evolved changes in mechanisms that alter the potential of populations to spread.
To assess the extent to which changes in mechanisms will be accurately reflected in changes in model parameters, we performed a benchmarking simulation.
Effects observed in sensitive target tissues can also be caused by exposure-related changes in mechanisms governing normal negative feedback regulation of endocrine tissues and hormone secretion; such effects may also influence the dose-response relationship depending on exposure duration.
In concentrated alkali, a change in mechanism is noted.
This change in mechanism was explained via Neuber's theory of stresses at a notch.
This change in mechanism as temperature increases is accompanied by a decrease in activation energy.
This drastic change in mechanism, together with a complete description of the reaction kinetics and thermodynamics, brought easy tuning and fine control on the reaction.
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