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In addition, the macroporous architectures not only favored the ingress of electrolytes but also compensated the large volume change of the active materials during the cycling.
The compact composite cathode not only showed large ionic and electronic conductivity, but also provided sufficient "free space" to compensate the volumetric change of the active materials during cycling.
Hydraulic fracturing to tap unconventional shale gas reservoirs causes a volume change of the active clay minerals matrix in the gas shale structure, resulting in the clogging of the tiny nanopores and consequently undermining the production of the shale gas.
In MtMCAT, the Cβ Oγ bond of Ser91 turns upwards, resulting in a different orientation and thus an overall change of the active pocket compared to other known MCAT enzymes.
A change of the active site from Cr3+OH− at high pH to Cr4+OH− at pH < 0 is proposed; protonation of Cr3+OH− to Cr3+OH2 suppresses the reaction on this site at pH < 3.94.
A micro-island structure of the active material was confirmed to be self-organized during the initial cycle, and such a structural change of the active material was compared with that of other Sn-based electrodes.
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A change of the active-site serine residue to alanine does not influence the oligomerization behaviour of the protease domain, as was shown for human HtrA2 and E. coli DegP [ 7, 9, 12].
Thus, besides altering the sultam to sulfonamide ratio during conversion of 2a as discussed above, this mutation can have also an impact on the stereoselectivity of the C H nitrene insertion process, likely due to the subtle change of the active-site environment in close proximity to the putative imido iron intermediate of Scheme 1 (see also Figure 2).
Changes of the active compound contents often result in different pharmacological activity and medicinal quality [ 16].
During a discharge, very fast changes of the active power occur.
The changes of the active phases were studied by operando XAS spectroscopy.
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