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In particular, the dimensional change of graphite block is different from each location in the core, since the neutron fluence of the blocks is different locally.
Both in situ Raman spectroscopy and ex situ X-ray diffraction were employed to detect the structure change of graphite electrodes caused by the electrochemical intercalation of ClO4−.
The damage and repair of SEI film mainly results from the volume change of graphite particle due to lithium insertion and extraction.
The dynamic structural change of graphite during the electrochemical lithium intercalation at 1/3 C was identified by an in situ high energy synchrotron XRD.
Thanks to the fast data collecting detector and high energy X-ray beam of this characterization technique, the detailed structure change of graphite was monitored.
The mechanism responsible for the improved electrochemical behavior was ascribed to the formation of a stable and compact passive film that can accommodate the volume change of graphite particles.
Similar(53)
In-situ XRD experiments reveal that structural changes of graphite are retarded as silicon carbon nano composite contents increased.
The results were compared with a dQ/dE vs. E curve of graphite to analyze how the structural changes of graphite affect the Li-ion insertion process.
Comparing the relationship between fractal dimension and resistance change, it can be found that the changes in fractal dimension and resistivity have a similar trend with the changes of graphite content.
The hairy pattern of geometry of the graphite@CNT composite not only improves the mechanics and conductivity of the electrode, but also has more room to accommodate the volume change of the graphite particle upon prolonged electrochemical cycles.
A comparative study of crystallographic changes of the graphite anodes mixed with SiOx (in short, graphite-SiOx) to the pristine graphite during the lithium insertion and extraction under a half-cell condition is conducted by using in situ XRD for the first time.
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