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We have shown that degree of blockiness and change in chain architecture have significant effects on surface energy values.
Also observed after annealing were broadening of the relaxation time distribution and the appearance of interfacial polarization, suggesting a change in chain conformation from random coil to a locally stretched state to form a nematic domain.
It would be interesting to verify whether the change in chain conformation and aggregation ability found in HAP in solution could be transposed to the multi-layered films obtained with chitosan.
Upon cooling below room temperature, an increase in splitting of the two WAXS reflections is observed, which indicates a further change in chain packing.
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Only small absolute changes in chain size probability densities with temperature are found.
Consequently, they are not caused by changes in chain constitution arising from transesterification.
Raman active vibrations in the 700 cm−1 region that are sensitive to changes in chain conformation were analyzed.
All of the product selectivity variations were shown to be related to changes in chain length dependent growth probabilities.
Besides, using successive self-nucleation and annealing (SSA) thermal fractionation technique, changes in chain structures induced by pre-shearing were obtained.
FT-IR spectroscopy has been used to follow changes in chain conformation of poly ethylene terephthalate) (PET) which occur during glass formation and physical ageing.
There are few changes in chain orientation for either phase when the films are further elongated to a strain of 300%; however, the PEO domains are slightly more oriented at the high strain values.
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