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Hydride delivery from the reduced nicotinamide cofactor occurs to the Re face of the carbonyl group when the large group L (aromatic ring) and the small group S (alkyl side chain) substitute the carbonyl as shown in Fig. 7.
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Peptides, in which X is a side chain substituted tryptophan residue, have agonistic activity.
A long chain substituted imidazolium ionic liquid, 1,2-dimethyl-3-octylimidazolium bis trifluoromethanesulfonyl)imide (MMOITFSI), is used as the electrolyte for reversible intercalation of Li into LiMn2O4.
The ionic liquids were a series of straight chain substituted imidazoliums, 1,2-dimethyl-3-R-imidazolium tetrafluoroborate, where R = propyl, butyl, decyl or hexadecyl.
Monolayers of alkyl side chain substituted preformed polyimides (BACBP/BPDA) exhibit behaviour different from that of other 'hairy-rod' polymers which were studied previously.
This AGP (310 × 103 g/mol), which is water-soluble, contains β-1,3-linked galactopyranosyl main chain substituted at O-6 position with side chains containing galactose and arabinose residues.
The organic thin-film transistors (OTFTs) based on C8-OPh-BTBT are fabricated to investigate the charge transport properties and compare with that of the alkyl side chain substituted semiconductor such as C12-Ph-BTBT.
In this paper, we report switching behaviors of organic thin films made from branch chain substituted oligomer with device structure of gallium indium eutectic cathode/organic layer(s)/anode (indium tin oxide, highly oriented pyrolytic graphite, copper or doped n-type silicon).
This enzyme is involved in a beta-oxidative pathway of long chain substituted phenolic degradation in Pseudomonas (Olivera et al. 2001), yielding short-chain phenylalkanoyl-CoAs such as cinnamoyl-CoA.
It thus appears that the introduction of octyl side chain substituted thiophene moieties to the parent compound does not alter the out-of-plane spacing in these thermally annealed thin films.
These authors showed by NMR experiments and methylation analysis that the α-glucan was composed of a (1→4 -linked main chain, substituted at O-6 by single units of α-glucose in the proportion 1→4 -linked
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