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In addition, they show that tropomyosin bends smoothly yet anisotropically about its distinctive helically curved conformation, without any signs of unfolding, chain separation, localized kinks, or joints.
The high relative photoluminescence efficiency was ascribed to the low carbonyl content, with a possible contribution from PPV chain separation, which minimizes radiationless interchain exciton formation.
Some of the antibodies were undergoing some degree of chain separation showing up as faster bands.
All locally unfold prior to or coincident with chain separation.
Correlation of this data with light scattering provides insight into the sequence of local unfolding in relation to chain separation and dissociation from the actin filament.
Reduction of the chain-bridging disulphide bond allows for chain separation and exposure of the catalytic site, which enhances the toxin's activity [22], [24], [25].
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This is almost totally independent of side-chain separation at 293 K, while the situation is more complex at 330 K.
The plasticizer structure influences the polymerplasticizer interactions which affect inter- and intra-chain separation and hence the free volume of the system.
It is represented by the target DNA strand (in a form of sequence of nucleotides), the collection of positions in this strand describing the places of main chains separation, and another collection of positions, describing the helper chains.
The difference in ionic radii of Mn2+ (0.67 Å) compared to Cd2+ (0.95 Å) results in shorter intra-chain separations between neighboring UV ions (U U=8.0 and 8.1 Å in 2, and 8.19 and 8.36 Å in 1) and between neighboring MII ions (Mn Mn=8.1 Å in 2, and Cd Cd=8.32 and 8.25 Å in 1).
A model based conceptually on the initial attachment of water to the polymeric structure (causing weight increase) followed by chain segment separation and subsequent leaching (leading to weight decrease) was developed and explains satisfactorily the overall behaviour.
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