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The synthesis of a novel ABC ternary segregated H-shaped copolymer is described, of which a central poly ethylene glycol) (PEG) chain is terminated on both sides by polystyrene (PS) and poly tert-butylacrylate) (poly tert-butylacrylate
At this point the chain is terminated, either by a combination of two chains or by a disproportionation reaction involving the transfer of a hydrogen atom from one of the growing chains to the other: The structure enclosed in brackets, −[CH2−CH2−]n, is the repeating unit of the polymer chain.
1H-NMR studies of the low-molecular-weight polyethylene fraction indicated fully saturated polymer, and this behavior is only possible when the polymer chain is terminated with aluminum which, upon hydrolysis, gives fully saturated material [44].
Propagation continues through polymerizable methacrylate groups until the growing kinetic chain is terminated via recombination with another radical or through hydrogen abstraction and disproportionation.
This chain is terminated by two [ZrO8] dodecahedra (Zr2 and Zr2′), which share a corner (O1) with the [ZrO8] and [TiO6] polyhedra of the zig-zag chain.
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Both chains were labeled with two different tags: a (His 6 was introduced at the C-terminal end of α chain, while β chain was terminated by c-myc.
The nascent chain was terminated with Boc-alanine.
Specifically, in the case of samplers with slow convergence such as STR, 4PB, and c4PB, each short chain was terminated before reaching the stationary distribution.
Further, it was observed that PAN chains were terminated by hydrated and sulphated complexes of Ce(III) while the termination of PMMA radicals took place by primary radicals because PMMAs were formed by emulsion polymerization kinetics.
In poly(propylene glycol) (PPG) the polymer chains are terminated by hydroxy groups.
In the second case, the living polyglycidol (Mn 8000 g/mol) or poly(glycidol-co-ethylene glycol) (Mn 6000 g/mol) chains were terminated by the chloropropyl groups of the surface leading to polymer brushes.
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