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In this work, we design a new class of naphthalenediimide (NDI -based small molecule acceptors by iNDI -based an NDI central core unit and A-D-A-D-A-type moiety.
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Two novel star-shaped D A-type small molecules of TPA–PQ–T anD A-type–2T were desmalld and synthesized, in which the hole-transporting moleculesof TPA PQ Tlandne (TPA PQ 2Tthiophene (T) or double thiophene (2T) were usedesigneds and donor unitsynthesizedinoxaline (PQ) moiety whichsed as centhel core and acceptor unit, respectively.
Aromatic diimides (NDI and PDI) were also widely employed as the central core or terminal unit for SM NFAs.
To investigate the effect of elongated conjugation on this system, thiophene and bithiophene units were systematically incorporated between the central core and end capped unit.
Dendrimers are a special class of hyperbranched polymers that emanate from a central core with repetitive branching units, thus having a special molecular structure and controllable size.
The findings show that both core unit interfaces examined play central roles in ultrastability.
An EPC colony-forming unit (CFU) comprises a central core of round cells that is surrounded by elongated spindle-shaped cells (Fig. 1b).
Dendrimers are unimolecular, monodisperse, synthetic polymers (<15 nm) with layered architectures that constituted of a central core, an internal region consisting of repeating units and various terminal groups that determine the three-dimensional dendrimer characteristics structures.
Most Nups are constituents of specific sub-complexes, which form the major structural units of the pore: cytoplasmic fibrils, central core and the nuclear basket (Figure 1a) [7], [7].
By incorporation of the dithienyl vinylene-fused indacenodithiazole-based core, TVIDTzPDI showed better planarity in the core unit with a dihedral 45.4° and 49.6° angle of between central core and the PDI.
We have varied non-linear 2,5-diphenylthiophene molecular core as a potential source of central unit of bent-core mesogens and for the first time introduced 3,4-diphenylthiophene central core in the design of V-shaped liquid crystals.
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