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Electrical characterization predicts that these compounds have potentials for use as solid oxide fuel cell electrolyte material.
This paper presents dilatometry results for Ce0.9Gd0.1O1.95, a common intermediate temperature solid oxide fuel cell electrolyte material, doped at the 1, 3, and 5 mol% level using nitrates.
The cerium oxide (CeO2) nanoparticles were chosen as a model because this metal oxide nanoparticle has several important applications, such as fuel cell electrolyte, catalyst, polishing materials, insulators, gas sensor, and UV blockers.
Variation in cell terminal voltage with temperature is a reversible change attributed to the reversible phenomenon of freezing of cell electrolyte which furthermore is confirmed through ex-situ measurement of freezing point of electrolyte extracted from tested cells.
We build on the success of phosphoric acid as a fuel cell electrolyte, by designing a variant of the molecular acid that provides increased temperature range without sacrifice of high temperature conductivity or open circuit voltage.
Differential scanning calorimetry (DSC) has been used to measure the thermal interactions between several binder materials and representative anode carbons both in the presence of cell electrolyte (EC:DEC/1M LiPF6+2 wt.% vinylene carbonate) and after washing/drying.
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Two types of fuel cell electrolytes, i.e., oxygen-conducting, and hydrogen-conducting electrolytes, are considered.
Gadolinium doped ceria is a well-known oxygen ion conduction material for solid fuel cell electrolytes.
Various mixtures of quaternary ammonium bromides, QBr, have been tested for use in zincbromine cell electrolytes.
Therefore, [dema][TfO] based materials are candidates for non-humidified mesothermal fuel cell electrolytes.
The result is "one of the more important discoveries lately" in the study of fuel cell electrolytes, says Jack Brouwer, associate director of the National Fuel Cell Research Center at the University of California, Irvine.
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