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In contrast with bioelectrode 1, bioelectrode 2 exhibits a marked catalytic response in presence of nitrates.
However, in the presence of 1 g l-1 FeCl3 an opposite catalytic response was detected (Figure 5A).
The largest magnetite nanoparticles (ca. 40 nm) exhibit the best catalytic response, either modified with iron or cobalt porphyrins.
The CV curves expressed a catalytic response of the in situ grown and directly used Pt NPs by observing high current density.
In order to improve the catalytic response, different parameters in the electropolymerization process are evaluated and buffer effects are investigated.
The results obtained confirmed that the dispersion of the Al2O3 particles is connected with catalytic response to a higher activity.
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Cyclic voltammetric results indicated that the AuNPs/SH/ITO electrode showed excellent electrochemical properties, and exhibited effective catalytic responses towards biomolecules such as glutathione (GSH).
The sequential drop dry CoTAPc MWCNTs modified surface gave better catalytic responses with a catalytic rate constant of 2.2 × 105 M−1 s−1, apparent electron transfer rate constant of 0.073 cm s−1, and a limit of detection of 2.8 × 10−7 M.
Whereas negligible catalytic responses were obtained with graphite electrodes modified by BCB-single-stranded DNA, high catalytic activity is obtained at electrodes modified by the complexes between double-stranded DNA and BCB.
The Au/ITO electrode exhibited effective catalytic responses towards biomolecules such as ascorbic acid (AA) oxidation and lowered oxidation potential of AA by 0.6 V when compared with the bare ITO electrode.
It is shown that in contrast to microcrystal deposits, 4-benzolyoxy-TEMPO co-immobilised within PIM-EA-TB give stable catalytic responses for both, stationary and rotating disc electrode systems and for oxidation of glucose, sorbitol, and sucrose.
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