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The observed catalytic cooperation between active centers was ascribed to a bifunctional catalyst and/or a remote control mechanism.
Kinetic studies, 'in situ' characterizations and H/D isotopic exchange experiments were separately performed on catalysts containing small Ru nanoparticles and catalysts containing larger particles, in order to elucidate the mechanism of catalytic cooperation.
The coexistence of macromolecular replicators and thus the stability of presumed prebiotic replicator communities have been shown to critically depend on spatially constrained catalytic cooperation among RNA-like modular replicators.
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The fundamental question of whether human telomerase catalytic activity requires cooperation across two TERT subunits remains under debate.
Often the cooperation between catalytic and non-catalytic kinase functions is needed to cause the full and correct biological effects.
This research may facilitate future studies on the cooperation and catalytic mechanisms of GPx and SOD.
Activation of surfaces may be classified as follows; (i) originally active surfaces, (ii) intermediates produced by reaction with surface atoms, (iii) formation of active sites with functional groups, (iv) formation of active surface compounds, (v) cooperation of multiple catalytic processes.
These results suggest that the designed pyrazole ligand motif actively promotes coordination of H2O during catalysis and that this metal ligand cooperation contributes to the catalytic activity of Ru complex 1.
Atom-resolved microscopy evidences disclose that such outstanding catalytic activity could be attributed to the synergetic cooperation between Ni phase and epitaxial graphene shell.
Compared to other scaffolds, macromolecules with their own advantages can endow enzyme models with enriched catalytic sites as well as the easy-achieved cooperation of the catalysis and recognition.
The superior catalytic performance was mainly attributed to both the cooperation of Cu0 and Cu+ species and the highly dispersed surface Cu0, thereby improving the adsorption and polarization of CO bond in GVL and the following dissociation of H2 to produce active hydrogen for the hydrogenation step during the catalytic transformation of GVL.
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