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The monomers were polymerized by Pd(0) catalyst to give the corresponding precursor polymer with M̄n≈5×103.
In the other process (called oxychlorination), ethylene, hydrogen chloride, and oxygen (or air) are heated in the presence of a copper catalyst to give vinyl chloride and water.
Aerobic oxidation of indolomorphinan 1 without a 4,5-epoxy bridge proceeded in the presence of platinum catalyst to give indoleninomorphinan 2 or quinolono-C-normorphinan 5.
The Suzuki-type polycondensation was conducted with a highly efficient heterogeneous catalyst to give conjugated polymeric nanoparticles which are soluble in a variety of organic solvents.
All pentene isomers hydrogenate over the Pd/Al2O3 catalyst to give predominantly n-pentane and a small amount of the trans-2-pentene isomer.
In the first step, the monoenic reagent reacts with hydrogen peroxide, in the presence of pertungstic acid, as catalyst, to give the corresponding diol (hydroxylation of the double bond).
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The key steps involved asymmetric hydrogenations of α-enamides using Burk's DuPHOS-based Rh(I) catalysts to give high enantiomerically pure α-amino acid derivatives.
In the reaction at 373 K, NO might be reduced directly by H2 both on Pt and Pd catalysts to give N2 and N2O.
1-Ethynyl-2-phenylethynylbenzene (2) was polymerized by W and Mo catalysts to give soluble polymers with Mn of 6300 71,900 in good yields.
Monomers 2 5 also polymerized with Ru carbene catalysts to give high-molecular-weight polymers (Mn ca. 34 000–240 000) in high yields (66 100%).
Three fluoride ion sources (i.e. KF, TBAF and CsF) were investigated, and all of them were effective as catalysts to give high-molecular weight linear products with good film forming property.
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