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This apparatus permits catalysis samples to be studied within the elastic instruments at ISIS while under vacuum, flowing atmospheres of up to 5 bar and at temperatures between 4 and 1,273 K.
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In the first catalysis cycle, sample ALD demonstrates an efficiency of 15.26%.
New developments include reaction systems for catalysis research, sampling from reactors, systems for high-throughput applications in synthesis, the handling of microorganisms or cell-culturing procedures, and more.
This work opens a new possibility for boosting electrochemical catalysis abilities of Co4N samples by the structure design.
The sample after catalysis was washed with DMF, and dried under vacuum, followed by exposure to the XPS operating vacuum.
Inductively coupled plasma optical emission spectrometry (ICP-OES) measurements of the solid confirm the absence of Co (Co/Cd atomic ratio in the solid less than (4.8±1.9)×10−4:1; in contrast to 0.44:1 in the entire sample before catalysis).
In the absence of a structure for Pep2 (or the Pep2 TreS complex), the mechanistic basis of the 3-fold (maltose) or 4-fold (ATP) increase of Vmax is not obvious, but complex formation might drive Pep2 into a conformation that favors catalysis by reducing the sampling of conformational states that are compatible with substrate binding but do not allow turnover.
Data provided by the literature recommended direct transmethylation of feed samples using acid catalysis based on HCl/MeOH or BF3/MeOH reagents [13, 16].
Studies on shape-dependent catalysis of the bare ceria samples toward CO oxidation indicated that the cube-shaped ceria nanoparticles show better catalytic activity than the nanospheres and the commercial micropowders.
Finally, three propylene-like EP copolymers (containing only isolated ethylene units) have been synthesised via metallocene catalysis in order to study samples which combine both relatively high molar masses and short n1.
As discussed above, AlkA exhibits rapid reversible εA-DNA binding without any commitment to catalysis, allowing it to quickly sample a structurally diverse set of damaged bases.
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