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The ring-opening polymerisation mechanisms are discussed in detail, including anionic, cationic, coordination, and enzyme-catalysed polymerisation.
Although it is difficult to distinguish an outer-sphere attack from an insertion process, this type of mechanism was suggested in the gold(i -catalysed hydroami -catalysedlkynes and allenes withydroaminationce cofrdinalkyneso nitrogen wandfound to be preferred under callenesc conditions in the presence of an excess of alkyne (Scheme 3).
The Au-catalysed direct allylic etherification reaction is thought to proceed 23 via coordination of the {Au PPh3)}+ fragment at the C=C π-bond of the allylic alcohol.
No coordination.
a, The four steps in the reaction catalysed by ACLY.
This is about coordination.
A failure of coordination?
It's about coordination.
Coordination polymerization.
"Coordination is more likely.
Coaches call it coordination.
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