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Likewise to the majority of such CAs, coordination of the zinc ion by three His residues and one H2O ligand represents the "closed" status.
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The Ca coordination shell and residue labels are shown in bottom panel.
Dimeric structures can also be generated easily from an orthotobermorite that has silicate chains where the bridging tetrahedra are adjacent to one another instead of staggered, but they suffer from the same Ca-coordination issue.
The Ca-coordination problem that is encountered with the orthotobermorite models derives from the fact that the silicate chains that are clasped to successive Ca O main layers are directly adjacent to one another (i.e. across the interlayer), as illustrated in Figs. 8 ▸(a) and (d).
The CA remove aluminum by coordination reaction to create abundant secondary pores.
"When you're building a building, there's coordination, you can't have the framer, the plumber, the electrician and all of the different contractors working at the same time," says Araujo.
Julianne Moore – Sadly this actress has no sense of coordination and can't piece together an outfit to save her life.
CA participated in the coordination of the study and helped to draft the manuscript.
Ed Roberts from Imperial College London, who led the study, said: "The karate black belts were able to repeatedly coordinate their punching action with a level of coordination that novices can't produce.
Subsequent experimental facts [42 45], Figure 11, also confirmed for the first time the approximate dimensions of the coordination "helical cavity" (ca. 6 EO units/sodium cation and ca. 7 units EO/potassium cation, respectively).
The average Ca O distance for the interlayer Ca (i.e. Ca3) is 2.39 Å, which is close to the value that would be expected for Ca in sixfold coordination; indeed, the maximum, average and minimum Ca O and Si O distances are all consistent with the values that are calculated from known structures of calcium silicate hydrates (Fig. 7 ▸).
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