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The adsorption of carbon trioxide, carbonate and bicarbonate is investigated on the 111, 110 and 100 surfaces of silver from a quantum mechanical point of view.
Adsorbed carbonate and carbon trioxide have the same formal charge of −1.5 electrons and the same geometry, which is very close to that of carbonate compounds.
Other uncommon oxides are carbon suboxide, the unstable dicarbon monoxide (C2O), carbon trioxide (CO3), cyclopentanepentone (C5O5) cyclohexanehexone (C6O6), and mellitic anhydride (C12O9).
This may limit the formation of highly reactive species such as hydroxyl radical or carbon trioxide anion radicals formed during decomposition of peroxynitrite and peroxynitrous acid [57].
While peroxynitrous acid decomposes homolytically to nitrogen dioxide and hydroxyl radical, the deprotonated form decays in the presence of carbon dioxide to nitrogen dioxide and carbon trioxide anion radicals [57].
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Then, carbon nanodots/tungsten trioxide was successfully applied to the degradation of methylene blue.
Herein we designed a simple and effective method for synthesizing carbon nanodots/tungsten trioxide nanocomposite with high photocatalytic activity.
In addition, carbon nanodots/tungsten trioxide could also be used to degrade rhodamine B and methyl orange.
Most importantly, the photocatalytic activity of carbon nanodots/tungsten trioxide did not exhibit obvious changes after five cycles.
The results indicate that carbon nanodots/tungsten trioxide has potential applications in the degradation of organic pollutants in industrial waste water.
Owing to the polyporous structure of the activated carbon, molybdenum trioxide forms in the pores and then grows along the preferential orientation to build MoO3/C nanobelts, in which the MoO3 nanoparticles and carbon are dispersed uniformly and combined firmly.
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