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Open image in new window Fig. 6 In situ Py-FTIR spectroscopy of meso-SAPO-11 by FW-200 carbon template (a) and Carbot carbon template (b).
The results of the TGA suggest that the carbon template could be completely removed.
The number after abbreviation indicates the weight ratio of carbon template to theoretical yield of SAPO-11.
This result could be explained that excessive carbon template constructs excessive multi-mesopores and possess poor thermal stability, leading to mesopore collapse during thermal treatment.
The upward turn with a hysteresis loop is indicative of the mesoporosity, which is obviously generated form the carbon template introduction.
Finally, the carbon template was removed through thermal treatment in an ammonia atmosphere to obtain SiC monoliths with ordered mesoporous structures.
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The dual carbon templates with different size obtained from carbonation of P123 and PU were used to direct mesostructure and macroporous architectures respectively.
Using highly ordered mesoporous carbon templates, Polarz and co-workers synthesized ZnO of 195 m2 · g−1 [21].
Fibreboards made of coir fibres were converted to carbon templates by controlled thermal processing.
According to the results, the mesoporous specific surface area and pore volume increase with the increase of the amount of the carbon templates, which indicate that more carbon templates introduction could construct more mesopores.
However, the samples with excessive FW200 carbon templates show a poorer nature of mesopore, which indicates excessive carbon templates construct excessive multi-mesopores with poor thermal stability, leading to the collapse of the mesopores, even to block the original micropores.
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