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Oxygen insertion and migration occurred at the more substituted carbon of compounds 19 22, thus giving access to normal lactones exclusively in very good ee with an enantioselectivity trend similar to that observed for CHMO from Acinetobacter sp. NCIMB 9871 (Stewart et al. 1996, 1998).
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Compounds and relevant amino acids (Tyr 355 and Arg 120) in sticks (carbon atoms of compounds were colored in green).
The interpretations of proton and carbon signals of compounds 1, 2, and 3 were largely consistent with previously described [ 34].
Replacement of the central chiral carbon atom of compound 63 with a nitrogen atom gave rise to an achiral template represented by compound 64.
In their native role, the nitroarene dioxygenases start degradative pathways by hydroxylating nitro-substituted, and adjacent unsubstituted carbons of nitroaromatic compounds.
Aspergilli can use a wide variety of carbon compounds as a carbon source for its growth.
In exchange, the symbiont will benefit from a permanent source of carbon compounds, products of the photosynthesis.
Their sand is composed not of silica, but either of ice or of carbon compounds.
In addition, 99 genes are predicted to encode proteins involved in the degradation and use of carbon compounds, approximately 60 of which are identified by the CAZy database as glycoside hydrolases [ 31].
aCarbon recovery is the ratio of carbon compounds produced divided by the carbon compounds consumed and is expressed as a percentage.
The symbiont appears to be capable of utilizing a number of carbon compounds and producing energy aerobically and anaerobically.
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