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Relational measurement theory is developed to include calibration and sampling.
A DATA packet also contains calibration and sampling rate data as well as channel number and battery voltage.
In this paper calibration and sampling are shown to be independent non-linear processes which do change measurement results.
In representational measurement theory, the current theory of all measurements, calibration and sampling processes are assumed to be a linear transformation of the coordinate system, of no effect.
The measurement changes caused by calibration and sampling are proven to be equal to the quantum measurement disturbance described by the universal uncertainty relation which has been verified by experiments.
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Calibration and sample solutions of cadmium, with and without uranium were prepared by mixing different volumes of standard solutions of cadmium and uranyl nitrate, both prepared in suprapure nitric acid.
The mixed solution was used to prepare the calibration and sample blends for the IDMS experiments.
The calibration beads were diluted in PBS in order to avoid pH-based differences in fluorescence per fluorescein molecule between calibration and sample measurements [ 37].
Signals derived from non-essential elements were identified by comparison of blank, calibration and sample concentrations, and eliminated prior to reporting.
The distance to model for each sample (Calibration and Testing sample) for the four different PCA models forming the SIMCA approach are presented in Fig. 6 together with the threshold level for class assignment (1.5).
Linear discriminant analysis was performed on spectra of 228 samples which were randomly divided into 138 samples for calibration and 90 samples for validation.
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