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This hydrogen, however, can rapidly diffuse out of the sample even at room temperature, with a calculated diffusion coefficient that agrees with literature results.
Salinity decreased by 0.03 yr−1 (Fig. 4a) and the calculated diffusion coefficient (Eq. 3) ranged between 10 5 to 10−4 m2 s−1 in the period 2006 2015 (Fig. 4b).
It is concluded that the reaction is diffusion controlled, the calculated diffusion coefficient being 6.4 ± 0.6 × 10−10 m2s−1.
The calculated diffusion coefficient for the case of aged specimens is the least possible value.
Further analysis is provided in following sections based on calculated diffusion coefficient and surface chloride content.
In the relaxed bulk, the calculated diffusion coefficient was 2.3 ± 0.3 (times ) 10(^{-5}) cm(^2)/s.
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The calculated diffusion coefficients — 2.8 3.0 × 10−5 cm2/s for copper and 4.4 4.5 × 10−5 cm2/s for cadmium ions — were independent of the initial concentration.
The calculated diffusion coefficients are in good agreement with experimental data.
The calculated diffusion coefficients agree well with the experimental data and with the results of former simulation studies.
The calculated diffusion coefficients (D) vary between (4.7 8.2)×10−9m2/min and (3.5 5.3)×10−9m2/min for initial oxygen concentration of 10 and 20 mg/l, respectively.
The calculated diffusion coefficients of water are higher than expected: 25°C, DH2O = 8.5±2 × 10−6 cm2 s−1 in 0.5 M KPF6, while in 0.25 M KAlCl4DH2O, 10±2 × 10−6 cm2 s−10−6
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