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The calculation indicates that 75 93% of the chemical driving force is consumed by the volume diffusion of Zn in the untransformed Cu matrix ahead of the moving boundary under the given experimental conditions.
However, the chemical driving force is partially consumed by the volume diffusion of Zn in the Cu matrix ahead of the moving boundary for the other experimental values of v at 623 773 K.
Assuming that the migration of the interface is controlled by the volume diffusion in the neighboring phases, the growth rate of the intermetallic compound due to the reactive diffusion between the primary solid solution phases in a semi-infinite diffusion couple at an appropriate annealing temperature was evaluated using an analytical solution of diffusion equations.
So, the two distinct levels of the effective activation energy suggest an existence of a rapid transition from the region dominated by the grain boundary diffusion with particle rearrangement to the region dominated by the volume diffusion.
Similar(56)
The experiments have been conducted to eliminate the resistance to crystal growth due to the volume diffusion by increasing the solution flow rate through the growth chamber.
The results show that round, scallop-type Cu6Sn5 grains with a strong texture form at the molten solder/Cu interface and that their growth is controlled more by grain boundary (GB) diffusion at the beginning of the reaction followed by volume diffusion, whereas the growth of Cu3Sn is only volume-diffusion-controlled.
The growth of the Al-rich phase at the grain boundaries is controlled by volume diffusion in the matrix phase.
Whereas the time exponent of growth deviated from one-half at each moment, the overall time dependence was dictated by carbon volume diffusion in austenite.
It was shown that the process is limited by nonsteady-state volume diffusion of zinc in the alloy.
Loss of argon by volume diffusion, supported by previously reported mineralogical and isotopic features of the Bo Va deposit may suggest that the Jurassic-Cretaceous (Yanshanian) tectonothermal events overprinted some deposits in the Song Hien domain.
The growth of the intermetallic layers was found to be governed by volume diffusion, which followed a parabolic rate law.
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