Relevant theoretical results wereobtained after taking into account the solvent effect by the so-calledsupermolecule-PCM approach.
The solvent effect manifested by the kp dependence on monomer concentration is stronger for SBAm than for SBE.
The chiroptical properties of F-PANI/-CSA in organic solvents were found to be affected by the solvent, probably due to the solvent effect to the polymer backbone, and the helical conformation was drastically reversed by change of the solvent.
Following this, a long, thin tube was applied to mix the CCC eluent with water by in-tube turbulence, to reduce the solvent effect.
Since exhaustive sampling of the full conformational space is beyond the reach of explicit-solvent simulations, the solvent effect is represented by a distance-dependent dielectric constant of the form ε = Rij (where Rij is the distance between particles i and j) [22].
The solvent effect was annulated by casting the discs containing the samples (PCV, CHV, CHL and EPE) before placing them in the agar.
The solvent effect was also simulated by using continuum model in order to investigate the influence of an aqueous solution enviroment on the protein oxidation reactions.
Different solvents were also tested to reveal the solvent effect.
