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An analytical method should not be influenced by the sample matrix.
Accordingly, sample-to-sample variations in the extraction and desorption efficiencies caused by the sample matrix, i.e., due to the presence of OM, can be compensated [8, 10, 18].
The minimum mean square error estimation (MMSE) criterion can be used to estimate the desired user propagation channel, while the covariance matrix can be estimated by the sample matrix inversion (SMI) approach [7 9].
All three assays were influenced by the sample matrix of cereal extracts to some extent, and matrix-matched calibrations are recommended for quantitative screening purposes.
Therefore, deuterated internal standards were utilized and were spiked to plasma samples prior to the sample pretreatment, to counteract any target ion suppression caused by the sample matrix.
There was also no significant qPCR inhibition by the sample matrix, as seen by a comparison of the Cq values for the IAC in samples and in sterile distilled water.
Similar(54)
However, LC/MS is more easily affected by changes in the sample matrix.
Perchlorate was resolved by high-performance liquid chromatography from the sample matrix, ionized by using negative electrospray ionization, and partially fragmented by mass spectrometry (MS).
Average LA-ICP-MS results obtained by Holá et al. for fish scales are generally higher than the corresponding solution nebulization ICP-MS data, which is also explained by the complexity of the sample matrix, i.e., analyte enrichment in the uppermost layer ablated from fish scales [ 63].
The analytical method involves addition of a Zn Zn double-spike to the samples prior to digestion, separation of Zn from the sample matrix by ion exchange chromatography, and isotopic analysis by multiple-collector inductively coupled plasma mass spectrometry.
In this method, colchicine molecules were sorbed on MOF-5(Zn -Fe2O4NPs sorbent by various mechanisms like ion exchange, hydrogen bonding and electrostatic, ᴨ-ᴨ, hard–hard and dipole-ion interaction followed by exposing sonication waves as incremental mass transfer agent and then the sorbent was separated from the sample matrix by an external magnetic fields.
More suggestions(15)
by the sample group
by the sample water
by the sample covariance
by the sample temperature
by the sample contrast
by the sample holder
by the sample proportion
by the sample material
by the sample size
by the weight matrix
by the sample injection
by the sample path
by the confusion matrix
by the sample magnetization
by the sample fluorescence
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