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As matter of the fact, the specific sorption, normalized by the amorphous fraction, does not depend on the crystallinity.
This can be explained by the amorphous fraction of the GrPyC material, which is supposed to be less conducting in comparison with graphite due to a strong electron scattering.
The XRD pattern of pure LDPE film (Figure 3b) shows two peaks at a 2θ value of 21.3° and 23.6° produced by the crystalline fraction of LDPE and the diffuse halo produced by the amorphous fraction.
It is demonstrated that one main effect of strain-induced crystallization is a partial relaxation of the strain experienced by the amorphous fraction, although stress-hardening is simultaneously observed.
In the case of the organic vapor, the value of sorption at low relative pressure is mainly dominated by the amorphous fraction present in the samples, not showing any preferential adsorption on the inorganic component.
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Three parameters – the melt conductivity, the volume fraction of the semicrystalline particles, and the amorphous fraction within these particles are obtained by fitting the theoretical equations to the experimental data.
The α peak obtained by TSDC shows the progressive decrease of the chain segments mobility in the amorphous fraction as ageing progresses.
Simultaneously, we observe a relative increase of the amorphous fraction with rH.
It is known that the I002 peak corresponds to the crystalline fraction and the Iam peak corresponds to the amorphous fraction [31].
Crystalline fraction found at approximately 520 cm −1 and the amorphous fraction at 480 cm −1, demonstrating a mixture of the two phases within the films.
An increase in the amorphous fraction of the TPU is usually sufficient to ensure good adhesion properties.
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by the amorphous carbon
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