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The stability of the dimer is essentially influenced by stacking interactions between two pairs of aromatic frames.
First, because 1 is uncharged its crystal packing is dominated by stacking interactions between aromatic moieties rather than hydrogen bonding or interpenetration.
Figure 14 Formation of supramolecular chains (yellow, green) in (12b) by N-H…O and O-H…O interactions and these chains linked by stacking interactions between TDC rings (represented as spacefilled models).
Two of these adjacent chains are linked to each other by stacking interactions between the two TDC rings (carboxylate thiophene ring of one chain and carboxylic acid thiophene ring of another) (Figure 14).
These modified nucleotides were incorporated into the middle positions of hairpin stem to form MB stabilized by stacking interactions between modified opposite bases [ 89].
A simple model that is helpful in understanding the physical properties of DNA treats each strand as a negatively charged wire, the pair held together by hydrogen bonds across opposite bases and stabilized by stacking interactions between successive bases.
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Two of the AB chains are again connected to an AB chain which are parallel to each other by stacking interaction between the thiophene ring of A chains.
We report the design and synthesis of a complex (η5-C5H4CH2Ph Ru η5-C5H4CH2Ph Ru CO 2 η1eS -DBTe concept that DBT binding through the S -DBT can be augmented by π–π stacking interactions between a pendant phenyl group on the cyclopentadienyl ring and the DBT ligand.
Two of these chains are again linked to one another by the stacking interactions between two carboxylic acids of each chain (Cg1-Cg1iii where Cg1 = S1,C2,C3,C4,C5 [symmetry code iii = 2-x,1-y,1-z]) (Figure 16).
The K-turn conformation is stabilized by base stacking interactions between adenosines of the AG base pairs and the canonical stem (Klein et al. 2001).
Additionally, this co-conformation is stabilized by the stacking interactions between the iodopyridinium moiety and the hydroquinone rings, in total agreement with the NMR findings.
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