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Ethoxylates can be transformed into polyether carboxylates by selective derivatization of terminal primary hydroxyl groups [carboxymethylation of the hydroxyl group with sodium chloroacetate (nonionic soaps)].
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It is based on the selective derivatization of monosaccharides by 1-phenyl-3-methyl-5-pyrazolone (PMP), UHPLC sepanalysisand MS analysis of the derivatives.
Free cholesterol (FC) and cholesteryl ester (CE) were quantified using a fragment ion of m/z 369 after selective derivatization of FC using acetyl chloride [42].
By changing the secondary reagent 1-ethyl-3- 3-dimethylaminopropyll) carbodiimide instead of sodium cyanoborohydride), 4-APEBA is also applicable to the selective derivatization of carboxylic acids.
The tag derivatization strategy is based on the selective derivatization of S-NO bonds with a stable tag that confers affinity for a specific resin.
Such scaffold contains three different functions suitable for selective derivatization and could find applications in the design of peptidomimetics.
The high reactivity of some sites of PFAF molecules can be used for their selective derivatization with various groups leading to various functional molecules like the first PFAF-based dyad (comprised of 70-10-1 andeptwo corexTTF two exTTF donor moieties).
Last, it will be shown how a simple switch of co-reagent (EDC instead of NaBH3CN) turns 4-APEBA into a selective derivatization reagent for aliphatic carboxylic acids.
The Hamas tactic is encouraged by selective condemnation of Israel.
This arrangement provides unique opportunities for protein engineering by functional derivatization of these nonimmunoglobulin-like tails.
Lipids were extracted from bacteria grown under each condition using modified Bligh and Dyer Extraction[28], followed by methyl derivatization of the lipids.
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