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Bioremediation by reductive dehalogenation of groundwater contaminated with tetrachloroethene (PCE) or trichloroethene (TCE) is generally carried out through the addition of a fermentable electron donor such as lactate, benzoate, carbohydrates or vegetable oil.
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It is well known that CCl4 induce liver toxicity is attributed to the reductive dehalogenation of CCl4, catalyzed by CYP450 in the hepatic endoplasmic reticulum, leading to the generation of trichloromethyl peroxy radicals (CCl3), which is reported to be an unstable complex and belongs to highly reactive species [ 50].
Although benzoate was never detected in the 3-CB amended mesocosm, it was presumably produced via the reductive dehalogenation of the parent substrate and rapidly consumed by Syntrophus species.
This catabolic reductive dehalogenation of organohalide compounds ("organohalide respiration") is catalyzed in Dehalococcoides by heterodimeric, membrane-bound enzymes called "reductive dehalogenases" [ 10].
Reductive dehalogenation of 1,2-DCA to ethylene was measured in all reactors.
In this study cobalamin was shown to be an important biomolecule for the reductive dehalogenation of PFOS.
Recently, a rapidly increasing number of bacteria has been isolated that is able to couple the reductive dehalogenation of various halogenated aromatic and aliphatic compounds like chlorophenols and tetrachloroethene to energy conservation by electron-transport-coupled phosphorylation.
Dehalococcoides spp. are responsible for the reductive dehalogenation of environmental contaminants and are candidates for engineered bioremediation.
Electrochemical reductive dehalogenation of chlorinated organic compounds in organic and aqueous solutions was studied.
It has been tested against reductive dehalogenation of organochlorine pesticides and insecticides [153 155] and several other toxic substances such as chromium [156] and arsenic [157].
Comparisons were made between H2 and acetate on the rate and extent of reductive dehalogenation of PCE.
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