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Network polymers were obtained by reductive coupling of silyl triflates with potassium graphite.
Near-edge X-ray absorption fine structure (NEXAFS) was used to investigate the reaction of benzaldehyde on reduced surfaces of TiO2(0 0 1) to form stilbene by reductive coupling of the carbonyl groups.
The authors proposed that the [4Fe 4S]2+/+ cluster was formed by reductive coupling of two [2Fe 2S] clusters at the subunit interface, and that the [4Fe 4S] cluster played a role in the reductive cleavage of SAM to initiate radical chemistry.
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Metal-catalyzed reductive coupling of olefin-derived nucleophiles: Reinventing carbonyl addition.
A novel method for the intramolecular bridging of calix[4]arenes, based on the reductive coupling of dialdoximes, is described.
However, the single crystal is far more active for the reductive coupling of formaldehyde to ethylene than the polycrystalline material.
Jarrett and co-workers further demonstrated that reductive conversion of [2Fe 2S] to [4Fe 4S] clusters involved rapid dissociation of iron followed by rate-limiting reassociation to produce the [4Fe 4S] clusters; this observation is also inconsistent with the previously proposed reductive coupling of [2Fe 2S] clusters to form [4Fe 4S] clusters.
Radioactive iodine monochloride or reductive coupling of [99mTc]pertechnetate using sodium dithionite was used for covalent modification of the protein.
Furthermore, novel enzymatic C C bond forming reactions have been identified like benzylation of aromatics, intermolecular Diels-Alder or reductive coupling of carbon monoxide.
Reaction between a β-diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules.
The mechanism of this conversion is currently unknown but likely involves a NifH-mediated, reductive coupling of the neighboring clusters on Δ nifH NifDK.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com