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The flexibilities of the self-supporting supramolecular polymeric membranes were enhanced by introducing hydroxyl groups or phenylene groups to the starting polymers (monomers).
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Natural polyols can be obtained by chemical modification of the vegetable oils introducing hydroxyl groups in an unsaturated triglyceride by hydroxylation of carbon-carbon double bonds and/or by alcoholysis of the triglyceride to obtain mainly a monoglyceride [3, 5].
The motion mode (slide or roll) of carbon nanotube on Si substrate can be tuned by the introduced hydroxyl groups' ratio on the interfaces and the speed of carbon nanotube.
In the first approach, 2-ethylhexanoyl functionalized-BNNTs (RCO2 BNNTs) were prepared by sonicating BNNTs with HNO3 to introduce hydroxyl groups (HO-BNNTs), followed by reaction with 2-ethylhexanoyl chloride for 120 h to form the 2-ethylhexanoyl esters.
An effective rout to introduce hydroxyl groups onto the side walls of pristine SWCNTs by means of plasma treatment technique has been demonstrated.
The PMbGs were also reacted with diethanolamine (DEA) to introduce hydroxyl groups.
The reason is similar to that the introduced hydroxyl groups between surfaces can tune the motion of carbon nanotube.
The treatment processes were repeated 3 times to introduce hydroxyl groups homogeneously on the side walls of SWCNTs.
However, the effect of introduced hydroxyl groups on the motion behavior of carbon nanotubes has not been reported until now.
This reaction yields an intermediate with the hydroxylated product coordinated to the molybdenum via the newly introduced hydroxyl group.
By introducing multiple hydroxyl groups to the fluorescent probes (perylene diimide derivatives) which builds up hydrogen bonds between the probe and polymer matrix, the dynamics is discovered to be retarded.
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