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Ursodeoxycholic acid can be prepared by electroreduction with high stereoselectivity.
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The most remarkable superiority of photoreduction is that it can be driven by visible light compared to electroreduction which is activated by applied voltage or thermal reduction with high temperature.
This result is interpreted as a consequence of carbon gasification driven by reaction with peroxide species generated by electroreduction of oxygen.
The character of the rate constants changes in the function of potential points at multi-stage process of Bi III) ions electroreduction as well as a different mechanism of Bi III) electroreduction in the solutions with low water activity in comparison with the solutions with high water activity.
In this study, we propose a simple method to obtain gold architectures with high catalytic activity for glucose oxidation based on previous electrooxidation and electroreduction of graphite surfaces.
In a second step, the best AuNP-modified electrodes were covered with an ultrathin organic film of bisthienylbenzene (BTB) generated by electroreduction of the corresponding diazonium salt.
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Electroreduction of phthalimide in water acetonitrile solution acidified with H2SO4 or HCl under controlled acidity conditions results in removal of two carbonyl groups and allows obtaining isoindoline selectively with high yield and current efficiency.
The electrochemiluminescent signal of this system was quite stable with time, and its mechanism was ascribed to the electron-transfer of GO colloid and SO⋅−4 radicals produced by electroreduction of S2O2−8 ions.
Electrosynthesis of glyoxylic acid by electroreduction of oxalic acid has long been well known.
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