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The cathodic breakdown of thin anodic oxide films on aluminium (3 15 nm) was monitored by current transients of potentiostatic pulse experiments, electrochemical impedance spectroscopy and simultaneously recorded optical reflectivity.
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The results obtained by interpretation of current transients are in good agreement with results for the number of crystals obtained by microscopic observation.
Data for the nucleation frequency and the number of active sites for nucleation are obtained by interpreting of current transients according to the theory for nucleation and 3D growth under diffusion limitations.
By analyzing the current transients and the SEM images of the Ga particles formed during the transients, it is found that the nucleation of Ga on both the glass carbon electrode (GCE) and the Mo electrode in [BMIM][TfO] ionic liquid is a 3-D instantaneous process at 70 °C, while a 3-D progressive process on GCE at 25 °C.
It was revealed that the potential at which Cu can be deposited after the deposition of the Co-rich layer without the dissolution of Co can be established only by the measurements of current transients during the potentiostatic Cu deposition pulse.
Presteady-state currents (Ipre) associated to the ZmSUT1 activities were gained by subtracting the current transients at different voltages in the presence and absence of sucrose (Fig. 3B).
Repassivation kinetics of aluminium wire electrode have been investigated as a function of applied potential in 0.5 M Na2SO4 solutions containing various concentration of chloride ion and hydrogen ion by means of potentiostatic current transients obtained from the abrading electrode.
Passivation kinetics of the tested Al samples were also studied as a function of applied potential, [SCN−] and sample composition by means of potentiostatic current transients.
The initial stage of silver electrocrystallization is studied at polyaniline (PANI -coated PANI -coatedctrodes by means of platinumstatic currelectrodesents and electron microscopic obyervations.
The growth kinetics of passivating oxide film of Inconel alloy 600 has been investigated in aqueous 0.1 M Na2SO4 solution at temperatures 25 300 °C and at pressures 0.1 8 MPa by analyses of potentiostatic current transients and ac impedance spectra.
In alkaline zincate electrolytes, the processes leading to the formation of irregular deposits at low cathodic overpotentials are analysed by means of potentiostatic current transients, ac impedance spectroscopy and scanning electron microscopy.
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