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Benefiting from recent progresses in materials chemistry, diverse PLCBCs have been designed and synthesized by controlled polymerization using different synthetic routes and strategies.
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It is possible to prepare PPP graft copolymers with complex macromolecular architectures by the use of macromonomers prepared by controlled polymerization routes, namely atom transfer radical polymerization or ring opening polymerization and may contain either bromine or the ester boronic functional groups, both useful, for example, in Suzuki polycondensation or Yamamoto coupling.
Li et al. synthesized polymers with azine as the basic structural unit by controlled polymerization of PPD [69].
The polymers are synthesized by free radical polymerization using proprietary controlled process techniques to ensure that the functional group chemistries of the constituent monomers are evenly distributed throughout the polymeric backbone.
The fabrication of the cationic stearyl-acrylate monolith (designated as cationic C17 monolith) with controlled porosity was achieved by free radical polymerization using the initiator 2,2′-azobisisobutyronitrile in the presence of a ternary porogenic solvent composed of cyclohexanol, ethylene glycol and water.
Firstly, 1 was synthesized by radical polymerization using AIBN.
Fig. 4 Scanning electron microscope image of polystyrene nanospheres synthesized by dispersion polymerization using ethanol as reaction medium with (a) 70 and (b) 75 °C as polymerization temperature.
Fig. 8 Scanning electron microscope image of polystyrene nanospheres synthesized by dispersion polymerization using ethanol as reaction medium at 70 °C as polymerization temperature.
Poly 3-alkylthiophene) fibers were obtained by electrochemical Poly 3-alkylthiophenethe described three-electrode cell.
A hydrogel matrix was formed from the fibrinogen-F127 adducts by free-radical polymerization using light activation (photo-polymerization).
PTSA-doped TANI/Fe3O4 nanocomposites have been prepared by oxidative chemical polymerization using APS as an oxidant.
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