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J was varied over a 40-fold range simply by altering the solvent.
Two new complexes, [Cu(L 2(CH3COO)2(H2O)] · 6H2O (1) and [Cu2(L)2(CH3COO)4] · 2C2H5OH (2) (where LN- 4-chlorophenyl -3-pyridinecarboxamide), have been synthesized by aLN- 4-chlorophenyl -3-pyridinecarboxamide
By altering the solvent vapor annealing, cross-linking, and rinsing processing steps, various hierarchical combinations of the three nanoscale morphologies can be achieved.
Structures of the coordination polymers of such Ag(I) synthons can be tuned (a) by altering ligand geometry, rigidity, or functionality, (b) by exchanging the counterions, or (c) by altering the solvent system.
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The multiple morphologies, including vesicles, large compound vesicles, large compound micelles (LCMs), and so on, were obtained by altering the solvents, solvent composition, annealing time, and copolymer composition.
Further modification by use of sulfone 41 c offered no improvement in terms of selectivity (entry 4) whilst additional experimentation using 41 b by altering the base, solvent and temperature (entries 5 7) used in the reaction also did not favour the desired E-isomer.
The morphology and three-dimensional (3D) structure were controlled by altering the co-solvent (ethanol) composition in the carbon dioxide non-solvent stream during the demixing induced process.
A supersaturated solution can be obtained by dissolving more substance than could normally be dissolved by the solvent by altering the conditions of dissolution, for example by changing the pH or temperature of the solution [ 15].
By altering the composition and concentration of solvent, it was shown that different morphologies and phases of WO3 nanorods can be achieved [29].
It was shown that by altering the concentration and composition of solvents, different morphologies having variant diameters, shape, and distribution can be achieved.
The morphology and size of the NaLa(MoO4 2 particles can be tuned in a controlled manner by altering the pH value of the initial solution, reaction temperature, and composition of solvent.
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