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In this report, we demonstrate the formation of one-dimensional supramolecular assemblies of small organic compounds aligned by a template polymer.
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The technique uses a template provided by a plastic polymer that organizes itself naturally.
They were prepared in hydrothermal conditions by a template method based on polymer periodic structures of the same geometry, and fabricated by a 3D printer using photocurable resin.
The chiral gels were almost quantitatively prepared after removal of the template polymer by hydrolysis of the ester groups.
The template polymer microspheres are a polymer of glycidyl methacrylate (GMA) cross-linked with ethylene glycol dimethacrylate (EGDMA) supplied by Nano-Micro TeChinaogy Chinany (Jiangsu, China).
The structure of the template polymer precursor was preserved by the substitution of the alumina cation as evident from the scattered dendrites.
template polymer.
A polymer such as a nucleic acid must be replicated by a template-directed polymerization process.
A silica polymer composite as an amphi-templating material was synthesized by a sol gel method using tetraethyoxy-orthosilicate (TEOS), P123 and divinylbezene (DVB) as a silica precursor, a template and a polymer precursor, respectively.
Cleavage of a model phosphate ester and supercoiled plasmid DNA by a Cu(I ·adenylated polymer template and preliminary mechanistic investigations are reported.
For the path-integral calculations, a helium atom was replaced by a classical ring polymer composed of polymer beads.
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