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Digermene formation is critically dependent on the stabilization of the intermediate germylene by a phosphane base.
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Synthesis and host-guest interactions with various metal ions of two molecular fluorescent probes containing either an aza-crown or a dialkylamino group and a phosphane oxide are reported.
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The choice of phosphanes as bases compared to N-heterocyclic carbenes is also important as phosphanes can easily be removed in order to release a free germylene, which can undergo dimerization or rearrangement reactions.
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The natural charge of the chlorine atoms seems to be unaffected by the phosphane ligands (–0.55 and –0.56 for M1 and M2, respectively).
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