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The electropolymerization potential of pyrrole increased with increased current density but the current efficiency remained relatively unchanged at 99 105%.
The field reduces the roughness of the copper deposit, but the current efficiency can be maximized by controlling the system galvanostatically, which allows a high copper deposition rate at overpotential lower than 0.5 V in the applied field, with smooth deposit quality.
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In pressure cells the gas filling effect can be eliminated as well, but surprisingly the current efficiency decreased with increasing pressure.
The addition of appropriate Me-EDA-Si can not only enhance the current efficiency but also inhibit the growth of semicircle-like grains, thus resulting in Pt electrode with high active surface area.
The results show that (1) It is the cation of the chemical activator, but not the anion that affects the current efficiency and the reaction selectivity.
The current efficiency was lower than 30%.
From measurements of the current efficiency kinetic parameters are deduced.
Accordingly, the current efficiency for film growth was decreased.
In this case the current efficiency is approximately 91%.
Additionally we report very good current efficiencies: in case of 80% water recovery, the current efficiency is 0.93.
The electrolyte is an acidic solution of zinc sulfide or zinc chloride with other bath additions to improve the quality of the coating and the current efficiency.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com