Emulsifiers with bulky tails favored the formation of planar microstructure.
Molecules with short amine-linked alkyl tails rapidly crystallize upon dissolution in water, whereas bulkier tails require the addition of salt to screen electrostatic repulsion and annealing to drive crystallization.
Interestingly, the compounds with the bulkier tails, 15 and 16, were more effective as hCA I inhibitors compared to the derivatives with the OH, OMe, or alkynyl-ether moieties 11141114
On the contrary, a bulky polar tail in type II kinase inhibitors is allowed.
The relatively bulky butyl "tail" of the diethanolamine ligand in (11), relative to teaH2− in (2) may block the extra site from becoming involved.
The slower adduct reaction is attributable to steric hindrance imposed by the bulky (–C5H11) alkyl tail of HNE (Friedman and Wall 1966).
For years I have been hearing rumours of a gigantic sauropod – think tiny head, long neck, bulky body and tapering tail – excavated from the southernmost reaches of Argentina by Drexel University paleontologist Kenneth Lacorvara and his team.
The kurtosis is generally understood to represent the "peakedness" of : a small kurtosis indicates bulky peak and sharp tails; a large kurtosis indicates narrow peak and heavy tails.
The closest contenders, whose tails are merely as bulky as their own bodies, include the common striped possum, which has a prehensile tail for climbing; the squirrel glider, which navigates with its tail as a rudder; and the ring-tailed cat, which uses its tail for balance during acrobatics in trees.
The lupine strand of the movie focuses on the love story of Seth (Lee Williams and Gabriel James Laytonon), two pouty young men whose wolfish identity is signified by their bulky fur coats and long fluffy tails.
