Cu II -IIPs were synthesized by bulk polymerization with Cu II -IIPss containing different anions (SO42−, Cl−, NO3− and CH3COO−) as templates, methanol as solvent, ethylene glycol dimethacrylate as crosslinking agent, and azodiisobutyronitrile as initiator.
Hyperbranched (hb) aromatic polyesters with phenolic end groups were synthesized according to the A2 + B3 approach both, by solution polymerization and by melt (bulk) polymerization with different monomer ratios (A2 B3).
Poly methyl methacrylate)/zirconia (PMMA/ZrO2) nanocomposites with ZrO2 content as high as 15 wt% were prepared by modifying non-aqueous synthesized ZrO2 nanoparticles with methacryloxypropyltrimethoxysilane (MPS) in tetrahydrofuran, dispersing MPS-functionalized ZrO2 nanoparticles in MMA and following in situ bulk polymerization with controlled pre-polymerization time.
This is consistent with the decrease in final conversions of bulk polymerizations with higher concentrations of nanoparticles noted in Fig. 6.
The bulk polymerization of HEMA, a monomer with a high value of dielectronic constant, can be well controlled with EPN-Br/CuCl/ bpy at 20°C.
Chitin/poly(glycidyl methacrylate) (PGMA) composites were synthesized via bulk polymerization in a gel state of chitin impregnated with reactive GMA monomer.
In this study, the bulk polymerization of a diyne and a bisazide were achieved through the copper-catalyzed alkyne-azide 1,3-cycloaddition (CuAAC) with different catalysts, including the homogeneous catalyst Cu PPh3)3Br and a heterogeneous Cu/C catalyst.
Additionally, the mole ratio of 1 3 give the highest ΔE, therefore, the polymer was synthesized by the thermal bulk polymerization method with the mole ratio of S-warfarin- MAA)3.
Induction time represents the period of time prior to bulk polymerization during which an initiation system generates sufficient radicals to overcome any inhibitory reactions.
The structure of PVC obtained from the bulk polymerization of VC with Cp∗Ti OPh 3/MAO catalyst consists of a regular structure.
