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By applying flow, i.e., replacing the water in the interfacial region by bulk solution, the interfacial ionic strength becomes dominated by the bulk electrolyte concentration.
Upon flow, i.e., mixing the interfacial region with a bulk electrolyte solution, the SFG signals drop according to the bulk ionic strength of the corresponding solution, similar to what is observed for pure water.
The temperature dependence of this resistance and that of the bulk electrolyte exhibit a similar discontinuity.
The total interfacial resistance is generally many times that of the bulk electrolyte.
Thus the effects of a possibly dominant bulk electrolyte impedance are eliminated.
This interesting coincidence suggests for correlation between the bulk (electrolyte) and surface conduction properties.
Typically these electrochemically induced side reactions generate the SEI layer, but inherent instability of the bulk electrolyte may also play a role in the formation of surface layers.
Similar(4)
Diffusional coupling effects result in overshoots and uphill ion diffusion in bulk electrolytes and within charged ion-exchange particles.
Bulk electrolytes and electrolytes near both inert and metallic surfaces are considered.
Salt transport in bulk electrolytes is limited by diffusion and advection, but in microstructures with charged surfaces (e.g., microfluidic devices, porous media, soils, or biological tissues) surface conduction and electro-osmotic flow also contribute to ionic fluxes.
The data obtained in the bulk electrolytes were used to determine the critical conditions in the thin-layer cell which impede the repassivation of the stainless steel (pH and [Cl−]).
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