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The presence of flexile SiC/S-graphitized carbon nanosheets (SiC/S-GCN) is able to buffer the large volume expansion and contraction of MnO/MnS nanoparticles during the cycling process.
Used as an anode in lithium-ion batteries, the carbon shell can help buffer the large volume expansion/contraction of the Si/C core during charge/discharge and restrain the capacity fading caused by the mechanical failure of the active material.
Hollow and mesoporous structures not only provide enhanced mechanical stabilities to buffer the large volume changes during the charge/discharge processes, but also provide large specific areas for sufficient penetration of electrolyte, thus leading to an excellent cyclic stability and rate capability.
The enhancement in the electrochemical performance could be attributed to the introduction of RGO sheets that not only buffer the large volume changes during the alloy/dealloy reaction of Li and Bi, but also provide a highly conductive network for rapid electron transport in electrode during electrochemical reaction.
The GF provides an elastic and robust three-dimensional structure to buffer the large volume change of Si, while the PR-pyrolytic carbon not only limits the huge volume change of Si, but also retains good contact with both the GF and Si to maintain electrode integrity.
The porous structure can buffer the large volume change and the agglomerations of electrode, which could be enhanced the cycling performance [16, 17].
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The good electrochemical performance can be attributed to its unique hierarchy architecture, which facilitates the ion transport and buffers the large volume change during the alloying/de-alloying reactions.
The well-connected three-dimensional mesoporous nanosheets array structure offers a large number of catalytically active sites and buffers the large volume change during the electrochemical process of OER and HER.
The 3D porous frameworks and coating graphene nano-shells serve as efficient electron and ion conductive networks as well as buffer for the large volume variation of hollow SnO2-Fe2O3 during cycling.
The amorphous carbon coating can not only effectively improve the electrical conductivity and durability of the ZnO nanosheets but also act as a buffer to accommodate the large volume strain during cycling.
Among these processes, foam architecture is attractive as an electrode structure in Li-ion batteries as it has an intrinsic structural integrity with the ability to buffer stress caused by the large volume changes in high capacity anode materials during cycling.
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