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Both cargos are shielded with a polymer brush structure of the nanoparticle shell, which prevents any enzyme substrate interactions.
At moderate grafting densities ensuring Gaussian elasticity of tethered stars the brush structure is described by strong stretching SS-SCF theory employing parabolic molecular potential.
Finally, we detail several specific applications of PGNP either in polymer nanocomposites or single particle systems, focusing on how the brush structure in particular enables the various applications.
We find that the key factor leading to the observed non-trivial brush structure is the grafting of the chains in the brush via the same end.
An ultra-high protein immobilization capacity (2600 μg streptavidin/mg SiO2@PAAs) was realized by virtue of its rich carboxyl groups and spherical brush structure, which opens up new possibilities for biomedical applications.
It is proposed that the stability of the micellar cores was increased with the macrocyclic molecular brush structure of the diblock copolymers and the formation of the MOSS aggregates via MOSS MOSS interactions.
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Polymer brush structures served as a flexible linker between HDPs and the surface while maximizing the density of peptides per coating [ 18].
After removal of the tert-butyl group, the study of the PLGA-b-PMLGSLG amphiphilic diblock copolymers in Langmuir monolayers and Langmuir Blodgett films demonstrated the formation of a stable α-helical double-brush structure, with the helices tilted away from the substrate surface.
We demonstrate that change in weight content of hydrolyzing agent, yield profound variations in the oxide microstructure, with plate and brush like structure.
The superior electro-capacitive behavior of the Co3O4-U0.37 wattributedtod to high surface area and brush like structure amongst studied Co3O4.
It remains possible that subtle changes are occurring in the absence of Lkb1, but that these do not result in obvious changes to brush border structure and nuclear localization.
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