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Δν mn and T2, mn represent the frequency shift and T2 relaxation time constant, which is inversely proportional to the line broadening for each resonance, respectively.
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The decreased broadening for PEGylated AuNPs is likely because of the decreased heterogeneity in NPC sizes within cells.
Thus, both of the resonance frequency differences are much larger than the maximum observed broadening for CO of ∼30 Hz.
T2, mn can be slightly different as imperfect decoupling can lead to slight line broadening for S13C, which does not play a role for S12C.
Data processing was accomplished using Bruker Topspin 3.1 software (Macintosh) using QSINE apodization, GB = 0.001, and line broadening for of –0.05Hz (f2) and -0.1 Hz (f1).
We determined angular momentum dependent collision broadening coefficients for each noble gas using the Lorentzian widths that were extracted from Voigt fits to the line shapes.
Opportunities have broadened for African-American art professionals.
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