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NMR conditions allow for the "ligand" and "receptor" concentrations to be kept much higher, thus permitting the probing of weaker affinity interactions observed via observation of changes in amide H/N chemical shifts, NMR signal intensity, and/or increases in spectral line broadening as a function of the progressive addition of one reactant to the other.
The average particle diameter, D, was obtained using Scherer's formula [22] for the peak width broadening as a function of the size of the particles.
Furthermore, we observe a peak broadening as a function of aging.
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The extent of enthalpy relaxation decreased and the distribution was drastically broadened as a function of TMPTA content due to molecular mobility restrictions, which were also quantified by measuring values for the apparent enthalpy relaxation activation energy (Δh*).
Further, the pulse broadening ratio as a function of propagation distance, for different input pulses is depicted in Fig. 4.
Since then the use of PRP has been broadened as an augmentation procedure for several applications.
The peak width is broadened as a result of the nano-size effect.
As a result, the SPR band(s) of aggregated gold NPs will be broadened and red-shifted as a function of the amount of analyte.
The average of fractional changes for the 40 most broadened resonances is plotted as a function of the concentration of GRG in Figure 2(A).
DNP enhancements increased with agent concentration up to 2.5 mM and decreased above 3 mM, in tune with ESR line broadening measured at X-band as a function of the agent concentration.
This small broadening of the bandgap as a function of substrate temperature can be attributed to quantum size effects.
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