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Like other condensation polymerizations, ADMET polymerization results in relatively broad molecular weight distributions (PDI ≈ 2.0).
The SMPs presented a broad molecular weight distribution from smaller than 1 kDa to over 100 kDa.
Extremely high molecular weight polyethylene could be produced (approaching 1 million Da), with industrially desirable, broad molecular weight distributions.
All of the investigated SMTAPE emulsifiers show two CMC break points, which were attributed to their broad molecular weight distribution.
However, there still remains disagreement on the origins of the broad molecular weight distribution (MWD) characteristic of these polymers.
The resultant copolymer with 1 gave relatively broad molecular weight distributions, consisting of high and low molecular weight copolymers.
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In addition, slow alkylation at lower temperature is also responsible for broader molecular weight distribution [26].
It then decreased slightly towards higher conversions, leading to a broader molecular weight distribution.
However, the molecular weight was decreased (M w = 16,100 g mol−1), and broader molecular weight distribution was observed [30].
Higher molecular weight (M w = 455,000 g mol−1) polyethylene with broader molecular weight distribution (102.9) was observed.
It has been well documented that RAFT miniemulsion polymerization has broader molecular weight distribution, compared with its bulk polymerization counterpart.
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