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These experiments had solid to brine ratios of 1 68 and 1 10 on g/g basis.
We model cement carbonation from an assemblage of portlandite, psuedowollastonite, brucite, hydrotalcite, Fe-hydrogarnet, and anhydrite estimated from the hydration of initial anhydrous cement composition using the experimental cement to brine ratios (Table 2).
At higher solid to brine ratios (1 10 g/g), where roughly 60% more cement reacted with brine (based on percent recovery of dissolved Mg and the initial amount of cement), the model captures the increase in dissolved Ca with cement carbonation and higher dissolved Al concentrations when amorphous Al(OH 3 is used to control Al solubility.
At low solid to brine ratios (1 68 g/g), calcite precipitation results in a decrease in dissolved Ca, brucite and hydrotalcite dissolution result in the recovery of dissolved Mg to initial values, and SiO2, Fe(OH 3 and boehmite precipitation limit the amount of dissolved Si, Fe, and Al as CSH, Fe-hydrogarnet and hydrotalcite dissolved during the carbonation process.
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- for a high ratio of cysts to brine (e.g. 20 to 50% cysts to brine ratio on a volume/volume basis when using small brine tanks), exchange brine 2 to 3 times over 48 h to compensate for dilution due to release of water from the cysts.
The effects of acids and asphaltenes appear to depend on the volumetric crude oil-to-brine ratio.
When to be considered as NPK fertilizer, struvite crystallized using magnesium chloride has a ratio of 10 9 0 and struvite crystallized using brine has ratio of 10 7.8 1.7.
Table 3 Struvite production from cow urine using brine at different ratios of mixing Sr no.
Total struvite produced from cow urine using brine with optimum ratio was approximately 40 g/L.
In another set of above experiment, after addition of cow urine and brine in different ratio, the final pH was adjusted to 9 using 5 N NaOH solution and then kept on a magnetic stirrer.
This includes the effect of number of effects and top brine temperature on performance ratio.
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