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Notably, one of the CO ligands is disposed in bridging position between the metal centers.
Introduction of a meta- or para-phenylene spacer between the two boron atoms precludes the 2-mercaptoimidazol-1-yl groups from adopting a bridging position so that the potassium salts K2[ mtEt 3B- m-C6H4 -B mtEt 3] and K2[ mtEt 3B- m-C6H4 -B mtEt 3] become readily accessible.
Moving from 1 to 2, the terminal site on Mg loses TMP [in the reaction released as TMP(H)] and gains an R′ ligand (switching from a bridging position), while the vacated bridging position is refilled by an ortho-deprotonated anisole ligand that binds in an ambidentate (C14 to Mg, O to K) arrangement.
In addition, the 18O in the product ester was located not only in the carbonyl group (CO) but also in the bridging position (COC); 18O exchange between benzaldehyde and MgO surface occurred not only in the adsorption desorption of benzaldehyde, but also in the dimerization process.
One of the three carbonyl ligands takes up a bridging position between the nickel and the iron centers.
In addition, brokerage measures how many times the ego occupies a bridging position through which two nodes, which are disconnected otherwise, are connected.
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Stability of AEC in the high temperature biochars is attributed to the presence of oxonium groups in bridging positions of arene carbon, which are sterically resistant to nucleophilic attack.
With regard to brokerage roles, coordinators — people who occupy bridging positions inside the same Ri — were more likely to be aged 65 to 74, male, with an elementary school education, and with better self-rated health.
While in the side bridged position, the lower horizontal reference rod of the alignment device was fixed at the height of the superior iliac crest.
The high in-/out-degree indicates that TS TFs tend to regulate a large number of targets, and that TS TFs are regulated by a large number of regulators, while the high betweenness values show that TS TFs locate to bridge positions through which many regulatory pathways pass.
The geometry of adsorption depends on the nature of the metallic site: on MgO the alcohol groups bind to the metal sites on quasi-top positions, while on CaO, SrO and BaO the molecule is located on bridging positions.
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