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In 2D-layer 2, the CPIDA3− ligands display a simple bridging mode with Cd II).
All four compounds feature a bis-monodentate bridging mode of the coordinated dicarboxylate moiety.
The ligands L adopt didentate bridging mode to coordinate to the metal ions in complexes 2, 3, and 5 7.
Aminopyridinato ligands are coordinated to Ti-metal center in typical η 2 manner as well as in bridging mode, giving a unique status to this molecule in the entire class of Ti-aminopyridinates [29, 35].
The structural diversities among 1 6 have been carefully discussed, and the role of counterion in the self-assembly of coordination polymer have also been well documented from the coordination affinity and bridging mode.
With a few exceptions, the large number of compounds structurally characterised contain μ1,5-dca bridging and display very weak antiferromagnetic coupling (Jbridging mode.
Similar(41)
But in (2) two different coordination modes like bidentate chelating and bidentate chelating bridging modes are observed.
In 1, the CPIDA3− ligands adopt chelating and bridging modes with Pb II) to possess a 3D porous framework.
The ligand induces two different coordination environments around copper(I) by switching between μ2- and μ3-sulfur bridging modes.
While L1 afforded monodentate, symmetrical and unsymmetrical chelating as well as bimetallic bridging modes in its complexes, L2 has been found exclusively in a bidentate chelating mode.
The different crystal structures were controlled by not only the different coordinating and bridging modes of the edtza or (datza)2− ligands but also simultaneously the formation of complementary intermolecular hydrogen bonds.
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